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MCQ Questions Class 12 The d-and f-Block with Answers - Set - 5
Question 1:
Which of the following ions has electronic configuration [Ar]3d6?
(a) Ni3+
(b) Mn3+
(c) Fe3+
(d) Co3+
Correct Answer – (D)
Question 2:
Consider the following statements
(I) La(OH)3 is the least basic among hydroxides of lanthanides.
(II) Zr4+ and Hf4+ posses almost the same ionic radii.
(III) Ce4+ can as an oxidizing agent.
Which of the above is/are true ?
(a) (I) and (III)
(b) (II) and (III)
(c) (II) only
(d) (I) and (II)
Correct Answer – (B)
Question 3:
A compound of a metal ion Mx+ (Z = 24) has a spin only magnetic moment of 15 Bohr Magnetons. The number of unpaired electrons in the compound are
(a) 2
(b) 4
(c) 5
(d) 3
Correct Answer – (D)
Question 4:
In which of the following cases, the stability of two oxidation states is correctly represented
(a) Ti3+ > Ti4+
(b) Mn2+ > Mn3+
(c) Fe2+ > Fe3+
(d) Cu+ > Cu2+
Correct Answer – (B)
Question 5:
Which one of the following statements concerning lanthanide elements is false?
(a) Lanthanides are separated from one another by ion exchange method
(b) The ionic radii of trivalent lanthanides steadily increase with increase in atomic number
(c) All lanthanides are highly dense metals
(d) Most characteristic oxidation state of lanthanides is +3
Correct Answer – (B)
MCQ Questions Class 12 The d-and f-Block With Answers
Question 6:
For d-block elements the first ionization potential is of the order
(a) Zn > Fe > Cu > Cr
(b) Sc = Ti < V = Cr
(c) Zn < Cu < Ni < Co
(d) V > Cr > Mn > Fe
Correct Answer – (A)
Question 7:
Identify the incorrect statement among the following :
(a) Lanthanoid contraction is the accumulation of successive shrinkages.
(b) As a result of lanthanoid contraction, the properties of 4d series of the transition elements have no similarities with the 5d series of elements.
(c) Shielding power of 4f electrons is quite weak.
(d) There is a decrease in the radii of the atoms or ions as one proceeds from La to Lu.
Correct Answer – (B)
Question 8:
Cuprous ion is colourless while cupric ion is coloured because
(a) Both have half filled p-and d-orbitals
(b) Cuprous ion has incomplete d-orbitaland cupric ion has a complete d-orbital
(c) Both have unpaired electrons in the d-orbitals
(d) Cuprous ion has complete d-orbital and cupric ion has an incomplete d-orbital.
Correct Answer – (D)
Question 9:
White silver surface turns black when O3 is passed over it. This is due to the formation of
(a) silver hydroxide
(b) freshly reduced silver which is black in colour
(c) silver oxide
(d) a complex compound of silver and ozone
Correct Answer – (B)
Question 10:
The colour of copper sulphide is
(a) Blue
(b) Black
(c) Red
(d) Green
Correct Answer – (B)
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